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铕配合物[C₅H₅NC₁₆H₃₃][Eu（TTA）₄]在改性介孔材料Si-MCM-41孔道中的组装研究

A Study on Assembly of a Rare Earth Complex [C₅H₅NC₁₆H₃₃] [Eu（TTA）₄] in the Channel of Si-MCM-41

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【Author】 XU Qing-Hong 1, LI Hong-Wu 2 , LI Lian-Sheng 1*, ZOU Yong-Cun 1, XU Ru-Ren 1 (1. Key Laborary of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130023, China; 2. Jilin Vocational Technology College of Communication, Changchun 130012, China)

【机构】吉林大学无机合成与制备化学国家重点实验室；吉林省交通职业技术学院；吉林大学无机合成与制备化学国家重点实验室长春130023；长春130012；长春130023；长春130023；

【Abstract】 It was proved by ICP, fluorescence spectra and N 2 adsorption that the rare earth complex [C 5H 5NC 16H 33] [Eu(TTA) 4] is in the channel of Si-MCM-41 in the course of assembly. The rare earth complex of 67.9% is in the channel, suggesting that the assembly of the complex molecular on the mesoporous MCM-41 was carried out mainly in the channel.更多还原