【摘要】 <正> 目前,铅钙锡合金已广泛用作阀控式铅酸蓄电池(VRLAB)的板栅材料.由于钙的存在,使铅钙锡合金阳极氧化时易形成高阻抗的阳极腐蚀层,并出现晶间腐蚀,电池循环充放电能力仍不理想.为克服铅钙锡合金作为正极板栅材料的不利因素,我们对能替代铅合金中钙的合金添加剂进行了研更多还原

【Abstract】 The anodic behavio of Pb-(0. 075%-0. 73%)Sm-0. 63%Sn and Pb-0. 088%Ca-0. 63%Sn alloys in sulfuric acid solution has been studied by using cyclic voltammetry, linear sweep voltammetry and impedance-time curves. The experimental results show that samarium in the Pb-Sm-Sn alloy can inhibit the growth of the anodic corrosion layer(PbO2) formed on the alloy. Moreover, the evolution of oxygen at the Pb-Sm-Sn alloy electrode is less than that at the Pb-Ca-Sn alloy electrode. 2 V-200 A·h VRLA batteries were manufactured by using the above two alloy positive grids separately. The corrosion layers formed on the positive gird surfaces after the life test of the batteries were observed by SEM. The results of the test show that the capacity loss of the battery with the Pb-Sm-Sn positive grids is significantly less than that of the battery with the Pb-Ca-Sn positive grids, and the longer floating charge life of the battery with the Pb-Sm-Sn positive grids is caused by the better corrosion-resistant performance of the Pb-Sm-Sn alloy with the anodic corrosion layer having a finer grain structure.更多还原