节点文献
噻唑取代的新氮氧自由基NIT2-thz及其配合物Ni(NIT2-thz)2Cl2的合成、晶体结构和磁性
Synthesis, Crystal Structure and Magnetic Properties of Ni(Ⅱ) Complex with a New Thiazole-substituted Nitronyl Nitroxide
【Abstract】 A new nickl(Ⅱ) complex containing the thiazole-substituted nitroxide radical with the formula Ni(NIT2-thz) 2Cl 2(NIT2-thz=4,4,5,5-tetramethyl-2-(2′-thiazole)imidazolin-1-oxyl-3-oxide) was synthesized and its crystal structure was determined. The magnetic property analysis indicates that there is strong antiferromagnetic interactions between Ni(Ⅱ) and radical(J=-71.82 cm -1).
【关键词】 噻唑自由基;
Ni(Ⅱ)配合物;
晶体结构;
磁性;
【Key words】 Thiazole nitroxide radical; Ni(Ⅱ) complex; Crystal structure; Magnetism;
【Key words】 Thiazole nitroxide radical; Ni(Ⅱ) complex; Crystal structure; Magnetism;
【基金】 国家自然科学基金 (批准号 :2 0 1710 2 5 ,90 10 10 2 8)资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年07期
- 【分类号】O641.4
- 【被引频次】2
- 【下载频次】138