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一种新型的一维杂化磷酸锌化合物（2,2′-bipy）₂·Zn₂（PO₄H）（PO₄H₂）₂的合成与结构表征

Synthesis and Characterization of a Novel 1-D Hybrid Zinc Phosphate （2,2′-bipy）₂Zn₂（PO₄H）（PO₄H₂）₂

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【Author】 YAO You-Wei 1,2, YANG Guo-Yu 1  (1. State Key Laboratory of the Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China; 2. Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130023, China)

【机构】中国科学院福建物质结构研究所；结构化学国家重点实验室；结构化学国家重点实验室福州350002；中国科学院长春应用化学研究所；稀土化学与物理开放实验室；长春130022；福州350002；

【Abstract】 Trying to transgraft the idea of adjusting polyoxometallates′ micro-structures by rationally designing structure building units composed of ligand and "secondary metal" to the synthesis of open-framework zinc phosphate results in a novel 1-D hybrid zinc phosphate, (2,2′-bipy) 2Zn 2(PO 4H)·(PO 4H 2) 2(FJ-10: Fujian Institute of Research on the Structure of Matter). X-ray single crystal analysis reveals FJ-10 belongs to a triclinic crystal system, space group P-1, a=1.038 18(6) nm, b= 1.230 41(7) nm, c=1.234 81(7) nm, α=97.207 0(10)°, β=109.411 0(10)°, γ=113.081 0(10)°, V=1.307 79(13) nm 3, R 1=0.039 9, wR 2=0.101 3. The topology structure of FJ-10′s framework is characterized by PO 3(OH) bridged 4-rings. FJ-10 exemplifies firstly the π-π stacking of hybrid chains whose structure-building units are involved in ZnO 3N 2. FJ-10 predicts the novel hybrid transition phosphates.更多还原