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球壳粒子悬浮系模型化研究——内部相参数对介电谱影响的数值模拟

Model Study on the Suspension in Spherical Shell-structure Numerical Simulation for the Influence of Inner Parameters on the Dielectric Spectroscopy

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【作者】 赵孔双疋田巧李子杰雷建平裘乐乐

【Author】 ZHAO Kong-Shuang , HIKIDA Takumi, LI Zi-Jie, LEI Jian-Ping, QIU Le-Lc(1. Department of Chemistry, Beijing Normal University, Beijing 100875. China; 2. Department of Chemistry, South China Normal University, Guangzhou 510631. China)

【机构】 北京师范大学化学系华南师范大学化学系华南师范大学化学系 北京 100875北京 100875广州 510631广州 510631

【摘要】 在Hanai理论基础上对球壳粒子悬浮系的介电模型进行了模拟研究,通过用C++的复数类对理论公式的程序化,建立了介电谱的介电参数与体系内部相参数的关系。所得的解析解可方便地模拟介电弛豫谱依不同相参数的变化曲线,计算并分析了内部参数对介电谱的模式以及介电参数的影响因素。

【Abstract】 A simulation study of suspension in spherical shell-structure was made on the basis of Hanai theory. An improved and intelligentized program for solving the tedious equations from Hanai theory has been written with C++ language and complex class, and been applied to the numerical calculations of permittivities and conductivities at different frequencies from 10 to 107 Hz. The dependence of dielectric spec-troscopy on the inner parameters of the system was obtained by an example actualized in a microcapsule suspension. The results show that the patterns of the spectroscopy can be reflected qualitatively by the electric and structural parameters of the constituted phases of the system.

【基金】 国家自然科学基金(批准号:20273010,29873015);教育部高等学校骨干教师资助计划资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年05期
  • 【分类号】O648
  • 【被引频次】4
  • 【下载频次】146
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