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模板法制备枝状Pt纳米线

Branched Platinum Nanowires Prepared by Using Template Method

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【作者】 孔令斌李梦轲陆梅郭新勇力虎林

【Author】 KONG Ling-Bin 1, LI Meng-Ke 1, LU Mei 1, GUO Xin-Yong 2, LI Hu-Lin 1* (1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China; 2. Key Lab of Lubrication and Functional Materials, Henan University, Kaifeng 475001, China)

【机构】 兰州大学化学化工学院河南大学润滑与功能材料重点实验室兰州大学化学化工学院 兰州730000兰州730000开封475001兰州730000

【Abstract】 Porous anodic aluminum oxide(AAO) templates, obtained by anodization of aluminum sheets at relatively high voltages, were used for fabricating branched platinum nanowires which copy the three-dimensional branching structure of the nanochannels in the template. The formation of these branched nanochannels is the characteristic of AAO templates grown at 60 V in 0.15 mol/L H2C2O4 solution. When AAO templates are grown at 40 V or lower, straight channels and platinum nanowires are obtained. Platinum nanowires array was alter-current(AC)-electrodeposited in AAO at a lower frequency(20 Hz) and increasing voltage(5-15 V). Compared with traditional AC electrodeposition condition, the deposition rate of platinum nanowires under this condition is slower and more controllable. Therefore, the platinum nanowires can perfectly copy the structure of the template. The as-obtained Al/AAO/Pt composite and branched platinum nanowires were characterized by X-ray diffraction(XRD) and transmission electron microscope(TEM), respectively.

【基金】 国家自然科学基金 (批准号 :60 1710 0 4)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年03期
  • 【分类号】TB383
  • 【被引频次】55
  • 【下载频次】391
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