节点文献
电喷雾质谱动力学方法测定磷酰化丙丙二肽的气相质子亲和能
Determination of the Gas-Phase Proton Affinity of N-Dipropyloxy-phosphoryl Alkyl-alanine by Electrospray Ionization Mass Spectrometry with the Kinetic Method
【Abstract】 In this work, the change of gas-phase proton affinity of alkyl-alanine through the phosphorylation reaction was studied by the electrospray ionization mass spectrometry with kinetic method. It was proved that the phosphorylation could increase the proton affinity of small peptide. A proposal that proton affinity increase might be responsible for the sensitivity improvement of small peptide in mass spectrometry has been provided.
【关键词】 气相质子亲和能；
电喷雾质谱；
磷酰化；
丙丙二肽；
【Key words】 Gas-phase proton affinity； Electrospray ionization mass spectrometry(ESI-MS)； Phosphorylation； Alkyl-alanine；
【Key words】 Gas-phase proton affinity； Electrospray ionization mass spectrometry(ESI-MS)； Phosphorylation； Alkyl-alanine；
【基金】 国家自然科学重点基金 (批准号 :2 0 175 0 2 6)资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年03期
- 【分类号】O657.63
- 【被引频次】3
- 【下载频次】82