节点文献
辅酶NADH模型物还原反应动力学的核磁共振研究
A Kinetic NMR Study of Reduction Mechanism of NADH Models
【Abstract】 The rate constant and kinetic isotopic effect(k H/k D) of the reduction of 2-bromo-1-phenylethylidenemalononitrile with NADH model were determined through NMR spectroscopy. The results were consistent with that the hydride transfer step of the reaction which was the rate-determining step, and were comparable to the results obtained through UV-Vis Spectroscopy reported previously.
【基金】 国家自然科学基金 (批准号 :2 0 0 72 0 36 ,2 9832 0 40 );中国科学技术大学青年基金资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2003年01期
- 【分类号】O657.2
- 【被引频次】1
- 【下载频次】139