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四种新的水杨醛缩氨基酞菁Schiff碱的合成及光学性质
The synthesis and properties of four novel salicylidene amino-phthalocyanines
【摘要】 以四氨基金属酞菁为原料,合成了四种新的Schiff碱C60H36N12O4M(M=Cu,Ni,Zn,Co),并用质谱、元素分析、红外、紫外对其结构进行了分析和表征.通过荧光光谱对其光学性质进行了研究,四个Schiff碱官能团及中心金属对其光学性质及稳定性有一定的影响.
【Abstract】 Four novel Schiff base were synthesized from 2,9,16,23-tetra-amino-phthalocyanine(Ⅱ).The structures of these compounds were studied by MS,IR,Elemental anaysis and UV-Vis absorbption spectra.The properties of them were studied by fluorescence spectra.Four Schiff base and the central metal have a influence on the properties and stabilities of phthalocyanines,four Schiff and the central metal have influence on the properties and stabilities of phthalocyanines.
【关键词】 酞菁;
Schiff碱;
合成;
荧光光谱;
【Key words】 phthalocyanine; Schiff base; synthesis; fluorescence spectra;
【Key words】 phthalocyanine; Schiff base; synthesis; fluorescence spectra;
【基金】 教育部高等学校骨干教师计划基金资助项目(教技司[2000]66号).
- 【文献出处】 分子科学学报 ,Journal of Molecular Science , 编辑部邮箱 ,2003年03期
- 【分类号】O625.6
- 【被引频次】16
- 【下载频次】223