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HZSM-5催化的多相酯化法合成氯乙酸甲酯

Heterogeneous Esterification for the Synthesis of Methyl Chloroacetate Catalyzed by HZSM-5 Zeolites

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【作者】 杨可武姜玄珍

【Author】 YANG Ke wu, JIANG Xuan zhen(Department of Chemistry, Zhejiang University , Hangzhou 310027, China)

【机构】 浙江大学理学院化学系浙江大学理学院化学系 浙江杭州310027浙江杭州310027

【Abstract】 The synthesis of methyl chloroacetate from chloroacetic a cid and meth anol over HZSM 5 and modified HZSM 5(i.e. HZSM 5A and HZSM 5B) catalysts has bee n studied. The reaction conditions have been optimized. Over 95% conversions of chloroacetic acid could be achieved at the optimum reaction conditions. The mod ified catalysts with higher acidity in weak acidic region showed relatively high catalytic activities.

  • 【文献出处】 分子催化 ,Journal of Molecular Catalysis , 编辑部邮箱 ,2003年03期
  • 【分类号】O643.32
  • 【被引频次】5
  • 【下载频次】172
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