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激光光解研究焦脱镁叶绿酸-a作为光活化农药的可能性

LASER FLASH PHOTOLYSIS OF PYROPHAEOPHORBIDE-AAND ITS POSSIBLE APPLICATION AS A PHOTOACTIVATED PESTICIDE

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【作者】 吴铁一苗金玲赵红卫窦大营王文锋姚思德陈志龙

【Author】 WU Tieyi MIAO Jinling ZHAO Hongwei DOU Daying WANGWenfeng YAO Side (Radiation Application Center, Shanghai Institute of Nuclear Research, the Chinese Academy of Sciences, Shanghai 201800)CHEN Zhilong (Faculty ofNaval Medicine, No.2 Military Medical University, Shanghai 200433)

【机构】 中国科学院上海原子核研究所辐射技术应用研究中心中国人民解放军第二军医大学海军医学系 上海 201800上海 201800上海 200433

【摘要】 利用激光光解时间分辨吸收方法,对蚕砂叶绿素中提取的焦脱镁叶绿酸-a的光化学性质进行了初步的研究。发现,该化合物在实验检测的波长范围内都有较强的吸收,且能产生较高量子产额的三重激发态。进而讨论它作为光活化农药的可能性。

【Abstract】 By use of time-resolved laser flash photolysis techniques, a preliminary study of the photochemical characters of pyrophaeophorbide-a derived from chlorophyll in silkworm excrement has been completed. It is found that these compounds have strong absorbance in all wavelength ranges under investigation, and produce excited triplet state with high quantum yields. Discussions were made on possible applications of the pyrophaeophorbide-a as photoactivated pesticide.

【基金】 国家自然科学基金(30070862)资助
  • 【文献出处】 辐射研究与辐射工艺学报 ,Journal of Radiation Research and Radiation Processing , 编辑部邮箱 ,2003年03期
  • 【分类号】TQ450
  • 【被引频次】5
  • 【下载频次】158
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