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催化动力学光度法测定富硒茶叶中痕量硒

Spectrophotometric Determination of Trace Amounts of Selenium(IV) in Tea by Catalytic Kinetics

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【作者】 王秀梅单金缓周海洋

【Author】 WANG Xiu\|mei1,2, SHAN Jin\|huan1*, ZHOU Hai\|yang1 (1.College of Chemistry and Environmental Science, Hebei University, Baoding, Hebei 071002; 2.Handan Agricultural College ,Handan,Hebei 057150)

【机构】 河北大学化学与环境科学学院河北大学化学与环境科学学院 河北保定071002邯郸农业高等专科学校河北邯郸057150河北保定071002河北保定071002

【摘要】 本文研究了Se催化过氧化氢氧化甲基橙反应体系测定痕量Se的方法。硒浓度在0~65.7μg/L范围内与褪色反应率lg(A0/A)呈线性关系。方法检出限为0.761μg/L。用于茶叶中硒的测定,结果较满意。

【Abstract】 Trace Se(IV) can catalyze the discolouring oxidizing reaction of methyl- orange with hydrogen peroxide in nitric acid medium. Based on this fact, new method of catalytic kinetic spectrophotometry for the determination of trace Se(IV) was established. The range of measurement was 0~65.7 μg/L. The sensitivity of the method was 0.761 μg/L. The method has been used to determine trace Se (IV) in tea with satisfactory results.

  • 【文献出处】 分析科学学报 ,Journal of Analytical Science , 编辑部邮箱 ,2003年05期
  • 【分类号】O657.3
  • 【被引频次】15
  • 【下载频次】187
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