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重质油和焦油的族组成分析

The Determination of Group Composition in Heavy Oil and Tar

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【作者】 令狐文生张昌鸣李允梅杨建丽刘振宇

【Author】 LINGHU Wen\|sheng*, ZHANG Chang\|min, LI Yun\|mei, YANG Jian\|li, LIU Zhen\|yu Chinese Academy of Sciences, Taiyuan 030001)

【机构】 中国科学院山西煤炭化学研究所煤转化国家重点实验室中国科学院山西煤炭化学研究所煤转化国家重点实验室 太原030001太原030001太原030001

【摘要】 本文采用高效液相色谱、气相色谱、过滤 称重联合分析法对含有溶剂的焦油、重质油的烃族组成进行了分析。给出样品的烷烃、芳烃、非烃和沥青质四大烃族组成,还给出了样品芳烃分布。

【Abstract】 The purpose of the this work is to identify specific group composition in heavy oil and tar using high performance liquid chromatography (HPLC) with ultraviolet (UV) and difference detectors. A Zorbax- NH 2 column (250 mm×4.6 mm i.d.) was employed. Hexane was used as the mobile phase with a flow rate of 1.5~2.0 mL/min. Aromatics and polar compound in heavy oil and tar were determined by UV detector and saturates were characterized by difference detector. Asphaltene was defined as hexane insolubles. Aromatics distribution in heavy oil and tar was also determined based on their elution times. The accuracy and reproducibility were satisfactory.

【关键词】 重质油焦油族组成
【Key words】 Heavy oilTarGroup of composition
  • 【文献出处】 分析科学学报 ,Journal of Analytical Science , 编辑部邮箱 ,2003年05期
  • 【分类号】TE622
  • 【被引频次】14
  • 【下载频次】455
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