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石墨炉原子吸收光谱绝对分析法测定催化剂及重油中的钒

Determination of Vanadium in Catalyst and Heavy Oil by GFAAS Absolute Analytical Method

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【作者】 查涛星蔡凌霜

【Author】 ZHA Taoxing1,2, CAI Lingshuang1*(1. College of Chemistry and Molecular Science, Wuhan University, Wuhan430072;2. Zhanjiang Dongxing Oil Enterprise Co. Ltd., Zhangjiang, Guangdong524012)

【机构】 武汉大学化学与分子科学学院武汉大学化学与分子科学学院 武汉 430072湛江东兴石油企业有限公司广东湛江 524012武汉 430072

【摘要】 本文以硝酸钙为钒的基体改进剂,用石墨炉原子吸收光谱测定了钒的特征质量,并将实验值与L’vov提出的特征质量计算方法算出的理论值进行了比较,两者基本吻合。在此基础上用绝对分析法测定了催化剂及重油中的钒的含量,分析结果与化学法测出的结果无显著差异。

【Abstract】 In this paper, theoretic calculation of characteristic mass of vanadium under experimental condition is performed by applying L’vov’s equation. The theoretical characteristic mass coincides with the experimental characteristic mass which was obtained by STPF using calcium nitrate as modifier. The developed method was applied to the determination of the content of vanadium in catalyst and heavy oil, and the determined values were in a good agreement with that obtained by chemical method.

  • 【文献出处】 分析科学学报 ,Journal of Analytical Science , 编辑部邮箱 ,2003年04期
  • 【分类号】O657.31
  • 【被引频次】4
  • 【下载频次】89
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