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负催化动力学光度法测定溴的研究
Study on the Determination of Trace Bromine by Minus Catalytic Kinetic Spectrophotometry
【摘要】 本文报道了溴 ( Br- )对溴酸钾氧化甲基橙 ( MO)褪色反应的负催化作用及其动力学分析 ,建立了测定痕量溴的新方法。方法的检出限达到 1 .0× 1 0 - 9g/ m L,线性范围 0 .5~ 1 .8ng/ m L,表观摩尔吸光系数 1 .0× 1 0 6 L·mol- 1·cm- 1。用于井水 ,精盐中痕量溴的测定 ,结果满意
【Abstract】 A new method for the determination of trace bromine ion is described. The method is based on its minus catalytic effect upon KBrO 3 oxidize methyl orange. The molar absorption coefficient is 1 0×10 6 L·mol -1·cm -1. The linar range of the determination for bromine is 0.5 ~ 1.8 ng/mL.The method has been used for the determination of trace bromine in well water and salt with satisfactory results.
【关键词】 负催化动力学光度法;
溴;
甲基橙;
【Key words】 Minus catalytic kinetic spectrophotometry; Methyl orange; Bromine;
【Key words】 Minus catalytic kinetic spectrophotometry; Methyl orange; Bromine;
- 【文献出处】 分析科学学报 ,Journal of Analytical Science , 编辑部邮箱 ,2003年01期
- 【分类号】O657.3
- 【被引频次】10
- 【下载频次】71