【摘要】 综述了自组装单分子膜作为模型体系在电化学电极过程中长程电子转移方面应用的一些重要研究成果。重点介绍了电子转移距离、电活性中心的微环境、膜表面分子的设计和状态等因素对长程电子转移的影响情况。展望了该领域今后的发展方向。更多还原

【Abstract】 Self-assembled monolayers (SAMs) present an ideal model for the studies of electrochemical electron transfer kinetics. In this paper, some important results in this field, especially some effect factors, such as the distance of electron transfer, the design of film molecules and structure, and the microenvironment of redox active species, on the electron transfer kinetics, are reviewed. The future directions of applications of SAMs in electrochemical electron transfer kinetics are also given.更多还原