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棒状薄层色谱/氢火焰离子化检测器复杂混峰谱图特征提取方法的研究及应用

Investigation and Application of the Method Abstracting Parameters from the Complex Thin Layer Chromatogram

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【作者】 杜国华杨海鹰顾洁蔺玉贵

【Author】 Du Guohua (Department of Applied Chemistry, Beijing Institute of Petrochemical Technology, Beijing 102617) Yang Haiying *, Gu Jie, Lin Yugui (Research Institute of Petroleum Processing, Beijing 100083) Abstract About 300 heavy oil samples from various petroleum processing were analyzed by thin layer chromatography/flame ionization detection (TLC/FID) technique. The characteristic variants of recognizing samples from their TLC/FID chromatograms were

【机构】 北京石油化工学院应用化学系石油化工科学研究院石油化工科学研究院 北京102617北京100083北京100083

【摘要】 分析了各种工艺的重油样品近 30 0种 ,通过各样品的薄层色谱图提取了谱图识别的特征变量 ,实现了由TLC FID谱图识别样品类型的目的 ,并采用偏最小二乘方法将谱图数据特征与洗脱色谱法 (elutingchromatography ,简称EC[2 ] 法 )进行了关联 ,从而用于重油样品的烃族组成分析 ,预测结果与EC法相符。

【Abstract】 ed, which were used to correlate with the results from the eluting chromatography (EC) by partial least squares (PLS) method. A suitable recognition and determination method was proposed based on those quantitative parameters and PLS. The results obtained by this method were compared with those from EC.

  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,2003年01期
  • 【分类号】O657.7
  • 【被引频次】4
  • 【下载频次】203
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