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碳纤维和二硫化钼混杂增强尼龙复合材料的摩擦学性能研究

TRIBOLOGICAL PROPERTIES OF HYBRID CARBON FIBER AND MoS2 REINFORCED POLYAMIDE 1010 COMPOSITES

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【作者】 王军祥顾明元朱真才葛世荣刘维民

【Author】 WANG Junxiang1, GU Mingyuan1, ZHU Zhencai2, GE Shirong2, LIU Weimin3 200030,China; 2. School of Mechatronic and Materials Engineering, China University of Mining and Technology, Xuzhou 221008, China; ics, Chinese Academy of Sciences, Lanzhou 730000, China)

【机构】 上海交通大学金属基复合材料国家重点实验室中国矿业大学机电与材料工程学院中国科学院兰州化学物理研究所固体润滑国家重点实验室 上海200030上海200030江苏徐州221008甘肃兰州730000

【摘要】 以注塑成型法制备MoS2和碳纤维混杂增强尼龙1010复合材料,采用MM-200型磨损试验机考察复合材料摩擦磨损性能。研究结果表明:在干摩擦条件下,MoS2和碳纤维混杂可显著改善尼龙复合材料摩擦学性能,较小载荷下复合材料磨损以轻微磨粒磨损和疲劳磨损为主,较高载荷下复合材料则以热疲劳断裂剥落磨损为主。摩擦过程中MoS2和对偶铁发生摩擦化学反应,生成和对偶底材具有较强结合能力的硫化亚铁和硫酸铁等,同时部分被氧化生成MoO3。

【Abstract】 All specimens of MoS2 and carbon fiber reinforced polyamide 1010(PA1010) composites were prepared by a micro injection machine. The friction coefficient and wear rate of composites were investigated with the ringblock test rig. The results show that hybrid fillers can considerably improve the tribological properties of PA1010 composites under dry sliding friction conditions. The dominant wear mechanisms of composites were abrasive wear and fatigue wear at a low normal pressure; the fatigue cracking and peeling due to thermal effect resulted in the severe wear of composites with the increase of normal pressure. The tribochemical reactions between MoS2 and counterface Fe were found to generate FeS2 and FeSO4 which were more effective to promote the adhesive strength to the counterpart, and also MoS2 was partially oxidized to MoO3 during sliding.

【基金】 国家自然科学基金资助项目(50071031);中科院兰州化学物理研究所固体润滑国家重点实验室开放基金资助项目(9910)
  • 【文献出处】 复合材料学报 ,Acta Materiae Compositae Sinica , 编辑部邮箱 ,2003年02期
  • 【分类号】TB332
  • 【被引频次】29
  • 【下载频次】414
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