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表面状态和处理对涂层下A3钢腐蚀和涂层失效的影响

EFFECT OF SURFACE PREPERATIONS BEFORE COATINGS ON UNDERFILM CORROSION AND DEGRADATION OF COATINGS ON A3 STEEL

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【作者】 徐永祥严川伟高延敏张森曹楚南

【Author】 XU Yong xiang,YAN Chuan wei,GAO Yan min,CHANG Sen,CAO Chu nan State Key Laboratory for Corrosion and Protection,Institute of Metal Research, The Chinese Academy of Sciences,Shenyang 110016,China

【机构】 中国科学院金属研究所金属腐蚀与防护国家重点实验室中国科学院金属研究所金属腐蚀与防护国家重点实验室 沈阳110016沈阳110016沈阳110016

【摘要】 采用模拟大气腐蚀装置 ,用挂片法研究了不同表面处理和表面状态、不同湿度对涂层失效的影响 .通过对基体金属的腐蚀形貌观察 ,微区元素分析 ,并结合傅利叶变换红外光谱 (FTIR) ,研究了金属在涂层下的腐蚀产物和涂层结构的变化 .同时探讨了金属在涂层下的腐蚀和涂层失效机理 .

【Abstract】 Effect of various surface preperations before coating processes for A3 steel substrates,including abrading with different emery-papers,polishing,phosphating and nonphosphating on underfilm corrosion and degradation of the coatings were studied by means of exposure in simulated atmospheric corrosion settings.Blister-degree and rust-degree of the samples were evaluated according to the ASTM d714 and D610 specifications respectively.The morphology of the surface after exposure was analysed by SEM and the corrosion products and structure of the coatings were studied by EDAX and FTIR.Mechanism of underfilm corrosion and degredation of the coatings was proposed.

【关键词】 涂层基体金属表面处理磷化腐蚀
【Key words】 coatingssubstrate metalsurface treatmentphosphatingcorrosion
【基金】 国家自然科学基金资助项目 (5 5 9710 5 0 );国家重点基础研究专项经费资助项目 (G19990 65 0 )
  • 【文献出处】 腐蚀科学与防护技术 ,Corrosion Science and Technology Protection , 编辑部邮箱 ,2003年04期
  • 【分类号】TG172
  • 【被引频次】11
  • 【下载频次】258
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