【摘要】 合成得到了6个新的混价羧酸钌配合物.测定了配合物[Ru2(μ Ac)4(NO3)(H2O)](1)的晶体结构.该配合物为零维配合物,单斜晶系,空间群为P2(1)/n,晶胞参数a=7.405(5),b=7.659(5),c=13.943(10)　 ,β=90.640(10)°,R1=0.0356,Rw2=0.0690.研究了配合物的红外光谱、电子光谱、电子自旋顺磁共振谱和变温磁化率.更多还原

【Abstract】 Six new mixed-valent diruthenium tetracarboxylate complexes have been synthesized. The crystal structure of has been determined by X-ray crystallography. exhibits non-polymeric structure, and crystallizes in the monoclinic space group P2(1)/n with a=7.405(5),b=7.659(5),(c=13.943(10)) ?,β= 90.640(10)° and Z=2. The IR, UV-vis,EPR spectra and the variable temperature susceptibility have been studied.更多还原