【摘要】 利用酯基锡与缺位Keggin结构阴离子SiW11O8-39反应,合成了8种新的杂多阴离子———有机锡配合物.M5[(R′OOCCHR″CH2Sn)(SiW11O39)]·xH2O(M=K+,(Me4N)+;R′=CH3—,CH3CH2—,n-Bu—;R″=H,CH3—),通过元素分析、IR光谱、UV电子光谱、1HNMR、TGA-DSC热分析等测试手段对标题配合物进行了表征和性质研究.更多还原

【Abstract】 Eight new heteropoly anion-organometallic complexes M5·xH2O(M=K+,(Me4N)+;R′=CH3-,CH3CH2-,n-Bu-;R″=H,CH3-) have been synthesized by the reaction of estertin with Na8SiW11O39·xH2OThe products were characterized and their properties were studied by elemental analysis,IR,UV,1 H NMR and TGA-DSC measurements.更多还原