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水-异丙醚-苯酚三元系46℃等温截面相图的实验测定
Experimental Measurement of Isothermal Section at 46℃ in Water-isopropyl ether-phenol ternary System
【摘要】 用气相色谱法实验测定了水_异丙醚_苯酚的三元系在46℃的等温截面相图。相图上呈现两个两相共存区域和一个单相区域。在46℃水和异丙醚存在两相,当逐渐溶入苯酚后,水富端很小,而醚相中异丙醚摩尔分数逐渐减小到25.4%,苯酚逐渐增加到29.0%,这表明在醚相中苯酚可达到较大溶解度。在46℃水和苯酚也存在两相,在三元系中异丙醚在水相和苯酚相中的溶解度都不大。该相图为工业上萃取提供了一定的基础工作。
【Abstract】 The isothermal section at 46℃ in water_isopropyl ether_phenol ternary system has been measured experimentally with gas chromatograph method.There are one single_phase region and two two_phase regions in the phase section.At 46℃,there exists two phases in water and isopropyl ether system. With phenol’s increasing in solution,the mole fraction of isopropyl ether decreases to 25.4% gradually and the mole fraction of phenol increases to 29.0% gradually in ether phase.It is shown that phenol can get to larger solubility in ether phase and it is very useful for industrial extraction.
【Key words】 ternary system; phase diagram; isothermal section; Water-isopropyl ether-phenol; gas chromatograph method;
- 【文献出处】 常熟高专学报 ,Journal of Changshu College , 编辑部邮箱 ,2003年04期
- 【分类号】O642
- 【被引频次】7
- 【下载频次】175