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陶瓷注射成型的一种新的脱脂方法——超临界流体脱脂

A New Method of Debinding for Injection Molding of Ceramics——Supercritical Carbon Dioxide Extraction

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【作者】 吴音; 司文捷; 金元生; 苗赫濯; 于恩平;

【Author】 Wu Yin 1 ,Si Wenjie 1 ,Jing Yuansheng 2 ,Miao Hezhuo 1 ,Yu Enping 3 (1.State Key Lab of New Ceramics and Fi ne Processing,Tsinghua Univ,Beijing 100084,China)(2.State Key Lab of Tribology,Tsinghua Univ,Beijing 100084,China)(3.Dept of Chem Eng,Beijing Univ.of Chem Eng,Beijing 100029,China)

【机构】 清华大学新型陶瓷与精细工艺国家重点实验室; 清华大学摩擦学国家重点实验室; 北京化工大学 北京100084; 北京100084; 北京100029;

【摘要】 介绍了陶瓷注射成型的1种新脱脂方法———超临界流体脱蜡。利用非极性分子有机物石蜡(PW)与极性分子有机物聚丙烯(PP)及少量硬脂酸(SA)组成有机粘合剂,在压力P=40MPa,温度T=58℃的超临界CO2流体中脱脂2h,石蜡萃取率大于80%,该方法可使陶瓷注射成型脱脂时间大大减少,脱脂过程缩短到通常脱脂的1/10。另外超临界流体脱蜡明显克服了传统热脱脂的变形,开裂等各种缺陷。

【Abstract】 This paper describes a new extractio n method using supercritical carbon dioxide fruit for the debinding proc ess of ceramic injection molding.In this method,the powder is mixed with non-polar mo lecules organic materials paraffin wax(PW),polar molecules organic ma-terials polypropylene(PP)and stearic acid.Supercritical carbon dioxide extraction at 58℃and 40M Pa was used to remove the binder.The extraction yield of paraffin wax can achieve 80%after 2hours.The binder can be removed by the supercritical c arbon dioxide extraction method in short time as compared to th e thermal debinding method.Using th is method,the debinding time can be reduced to a bout one tenth.Besides,it is obvious to overcome the distortion,cracking and many kinds of defects during thermal debinding in ceramic in jection moldings.

【基金】 国家“973”项目资助(G200067203-2)
  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2003年01期
  • 【分类号】TQ174
  • 【被引频次】25
  • 【下载频次】379
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