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聚合物驻极体材料研究的新进展
New Progress in Polymeric Electret Materials
【摘要】 综述了几种电活性聚合物近年来的迅猛发展状况.其中之一是空间电荷型聚合物压电膜,例如聚丙烯蜂窝膜(PP cellular)和聚四氟乙烯多孔膜(porous PTFE),它们呈现出高达200~600pC/N的压电d33系数。另一类是经缺陷结构修正的弛豫铁电聚合物偏氟-三氟乙烯共聚物,它们在150MV/m的电场作用下可能诱导出约5%的高应变量和1J/cm3的高弹性能密度。而全有机复合材料则呈现出十分高的介电系数(>900),和在13MV/m的较低电场下形成的2%的高应变量及接近1GPa的高弹性模量。
【Abstract】 In this report,several classes of electroactive polymer developed recently are reviewed. As representative polymeric piezoelectric films with space charge, polypropylene cellular and porous polytetrafluoroethylyne films have a piezoelectric d33 coefficicent of 200 - 600pC/N. In the second class of electroactive polymers, i. e. the defect-structure modified poly(vinylidene fluoroethylene-trifluoroethylene) polymers,an electrostrictive strain of more than 5% and elastic energy density above 1J/cm3 can be induced in a field of 150MV/m. And the polymer is an all-organic composite,with a very high dielectric constant(>900) and high strain induced in a weak applied electric field (2% strain in 13MV/m) and the composite has an elastic modulus near 1GPa.
- 【文献出处】 材料导报 ,Materials Review , 编辑部邮箱 ,2003年05期
- 【分类号】TM22
- 【被引频次】3
- 【下载频次】467