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丁酸异戊酯的合成研究进展

Progress in Catalytic Synthesis of Isoamyl Butyrate

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【作者】 张余胡应喜

【Author】 Zhang Yu Hu Yingxi(Department of Chemical Engineering, Beijing Institute of Petro-chemical Technology, Beijing 102617)

【机构】 北京石油化工学院化学工程系北京石油化工学院化学工程系 北京 102617北京 102617

【摘要】 丁酸异戊酯是无色透明液体,具有香蕉和梨的香味,多用作食品和化妆品的香精,另外丁酸异戊酯还用于喷漆、清漆、硝酸纤维素、氯丁橡胶、油墨等溶剂,药品生产中的萃取剂等,用途较为广泛。介绍了三氯化铁、氯化亚锡、硫酸钛、硫酸铝、一水硫酸氢钠、对甲苯磺酸、氨基磺酸、固体超强酸、杂多酸、阳离子交换树脂、HY分子筛等催化剂催化合成丁酸异戊酯酸的方法,并对各催化剂的性能、优缺点进行了分析。

【Abstract】 Isoamyl butyrate is a colorless transparent liquid, which has sweet-smelling of banana and pear, and is widely used as food and cosmetics essence. In addition, isoamyl butyrate is used as a good solvent in spray paint, varnish, cellulose nitrate, chloroprene rubber and printing ink, and as extraction agent in the production of medicines and chemical reagents. The catalytic synthesis of isoamyl butyrate with ferric chloride hex hydrate, stannous chloride dihydrate, aluminum sulphate octadecahydrate, sodium bisulfate monohydrate, p-toluene sulfuric acid, amino-sulfonic acid, solid super acid, heteropoly acid, strong acidic cationic exchange resin and HY zeolite molecular sieve are reviewed. Advantages and shortcomings as well as catalytic properties of each catalyst are analyzed.

【关键词】 丁酸异戊酯催化剂合成
【Key words】 isoamyl butyratecatalystsynthesis
  • 【文献出处】 北京石油化工学院学报 ,Journal of Beijing Institufe of Petrochemical Technology , 编辑部邮箱 ,2003年03期
  • 【分类号】O623.624
  • 【被引频次】1
  • 【下载频次】200
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