【摘要】 以乌洛托品为起始原料,经硝化、氯化、叠氮化反应合成出了1,7-二叠氮基-2,4,6-三硝基-2,4,6-三氮杂庚烷(DATH),总收率为75.3%;测试了DATH的部分理化及爆轰性能,其密度1.71g/cm3,熔点135～137℃,爆速8300m/s(1.64g/cm3),燃烧热10822.02kJ/kg,分解温度192℃,摩擦感度12%(25kg/cm3,66°),撞击感度95%(12kg,25cm)。更多还原

【Abstract】 1,7diazido2,4,6trinitro2,4,6triazoheptane was synthesized with urotuopine as primary substance by nitration, chlorization and azido substitution steps in turn, the yield is 75.3%. the properties of DATH have been experimentally studied, its density 1.71 g/cm3, melt point 135～137 ℃, detonation velocity 8300 m/s(1.64), heat of combustion 1.08×104 kJ/kg, temperature of decomposition 192 ℃, friction sensitivity 12%(25 kg/cm2, 66°) impact sensitivity 95%(2 kg, 25 cm).更多还原