【摘要】 同种类型金属硫化物溶解度的大小主要取决于离子极化作用和阳离子水合焓,在某些硫化物中可能离子极化作用或阳离子水合焓单方面起决定作用,而另一些硫化物中这两种因素均不可忽视。更多还原

【Abstract】 Thermodynamic factors influencing solubility of insoluble sulfides with dx cations were studied considering ionic polarization energy, hydration enthalpy, entropy effect and so on. Solubility of the congeneric sulfide is determined by polarization effect and hydration enthalpy of the cation primarily, one of them is the only decisive factor in some sulfides, and both of them are important in others.更多还原