【摘要】 报道了3-氧杂-1,5-二戊醇二对甲苯磺酸酯及1,4-丁二醇二对甲苯磺酸酯与N-三甲基硅基对甲苯磺酰胺在碱存在下反应分别得到N-对甲苯磺酰基吗啡啉和N-对甲苯磺酰基四氢吡咯这一新的有机硅胺与磺酸酯的反应,在相同条件下N-三甲基硅基-对甲苯磺酰胺与对甲苯磺酸甲酯反应后仅得到N-甲基对甲苯磺酰胺,对此反应提出了可能的反应途径。更多还原

【Abstract】 N - p - tosyl - mopholine or N - p - tosyl - tetrahydropyrrole and N - methyl - p -toluenesulfonamide were prepared by the reactions of N - trimethylsilyl - p - toluenesulfonamide with 3 - oxa -1,5 - pentadiol ditosylate or 1,4- butadiol ditosylate and methyl p - tosylate respectively. The possible pathway was suggested.更多还原