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Ph₂C（OH）CH=CHSnAr₃的卤化物的合成、表征和性质

Synthesis, Properties and Structure of the Halides of (Z)-3-triarylstannyl-1,1-diphenyl-2-propenyl-1-ol

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【Author】 ZHU Dong - Sheng, , DAI Hui - Chong, SAN Xi-Lin, FU Fang-Xin, PAN Hua-De (Department of Chemistry, Northeast Normal University, 130024 Changchun)

【机构】东北师范大学化学系；东北师范大学化学系长春130024；长春130024；长春130024大庆石油学院化工系；黑龙江；安达； 151400；长春130024；

【摘要】首次以非碳环醇（Z）-3-三芳基锡基-1,1-二苯基-2-丙烯基-1-醇[Ph₂ C（OH）CH=CHSnAr₃]和卤素或拟卤素发生取代反应得到卤化物,并以此合成了氢氧化物、氧化物和配合物。通过元素分析、IR和¹H NMR等对上述17种新化合物的结构进行了表征,并提出了卤化物的性质。更多还原

【Abstract】 the reaction of the compound (Z) - 3 - triaiylstannyl -1,1 - diphenyl - 2 - propenyl - 1 -ol with ICl,Br2,I2 formed organotin halides,which reacted with KOH to form organotin oxide or hydroxide.The complexes were obtained by the organotin halides with three ligandrs (2,2’ - bipyridyl, 1,10 - phenanthroline, 8 - hydroxyquinoline). The seventeen new compounds were characterized by means of elemental analysis, IR and 1H NMR.Studied on the properties of the halides.更多还原