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铬(Ⅵ)-碘化钾-结晶紫体系的共振瑞利散射及其分析应用

Resonance Rayleigh scattering of chromium(Ⅵ) iodide crystal violet system and its analytical application

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【作者】 刘芹; 刘绍璞;

【Author】 Liu Qing Liu Shaopu(Institute of Environmental Chemistry,Southwest China Normal University,Chongqing 400715)

【机构】 西南师范大学环境化学研究所;

【摘要】 研究了铬(Ⅵ)碘化钾结晶紫体系的共振瑞利散射光谱,考察了它们的光谱特征、影响因素和适宜的反应条件.确定了散射强度与铬(Ⅵ)的浓度关系,提出了用RRS光谱间接测定痕量铬(Ⅵ)的新的高灵敏方法.

【Abstract】 he spectra of resonance Rayleigh scattering of chromium(Ⅵ) iodide crystal violet system,the affecting factors and optimum conditions of the reaction,and the quantitative relation of the I RRS to the concentration of Cr(Ⅵ) have been investigated.The concentration of Cr(Ⅵ) is proportion to the ΔI RRS in the 0~125μg/mL.The method has very highly sensitivity,the detection limit of Cr(Ⅵ) is 0 065ng/mL.The new analytical way for indirect determination of trace amounts of Cr(Ⅵ) by RRS was proposed.

  • 【文献出处】 西南师范大学学报(自然科学版) ,JOURNALOF SOUTHWEST CHINA NORMAL UNIVERSITY(NATURAL SCIENCE) , 编辑部邮箱 ,1998年03期
  • 【分类号】O657.3
  • 【被引频次】31
  • 【下载频次】144
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