节点文献
含有弱金属-氮键的磷钼酸有机衍生物的研究
Study on organic derivatives of phosphomolybdic acid with weak metal nitrogen bond
【摘要】 [(EDTB)M](CH3COO)2和H3PMo12O40在无水乙醇中反应得到[(EDTB)M](HPMo12O40),M为Cu、Co,EDTB为N,N,N′,N′-四[(2-苯并咪唑)甲基]-1,2-乙二胺。测定了它们的IR、HNMR、紫外-可见光谱和元素分析以及对酯化和乙酸环己酯热消除反应的催化活性。
【Abstract】 HPMo 12 O 40 ),M=Cu,Co,were prepared by the reaction of (CH 3COO) 2 with H 3PMo 12 O 40 in absolute ethanol, in which EDTB is N,N,N′,N′ tetrakis[(2 benzimidazolyl) methyl] 1,2 ethanediamine. The structure of the title compounds was characterized by IR, HNMR, UV Vis and elemental analysis, and the catalytic activities of pyrolytic elimination of cyclohexyl acetate and esterification were also determined.
【关键词】 磷钼酸有机衍生物;
弱金属-氮键配合物;
四[(苯并咪唑)甲基]乙二胺;
热消除;
【Key words】 organic derivative of phosphomolybdic acid; weak Cu(Co) N bond complex; tetrakis(benzimidazolyl methyl)ethanediamine; pyrolytic elimination;
【Key words】 organic derivative of phosphomolybdic acid; weak Cu(Co) N bond complex; tetrakis(benzimidazolyl methyl)ethanediamine; pyrolytic elimination;
【基金】 国家教委留学回国人员基金
- 【文献出处】 现代化工 ,MODERN CHEMICAL INDUSTRY , 编辑部邮箱 ,1998年02期
- 【分类号】O627
- 【被引频次】2
- 【下载频次】48