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某些有机物在氧化物载体表面的自发单层分散

Spontaneous Monolayer Dispersion of Some Organic Compounds on Oxide-supports

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【作者】 王小勇王敏赵壁英谢有畅

【Author】 Wang Xiaoyong; Wang Min; Zhao Biying; Xie Youchang(Institute of Physical Chemistry, Peking University, Beijing 100871)

【机构】 北京大学物理化学研究所!北京100871

【Abstract】 XRD and FT-IR methods were applied to the studies of organic monolayer dispersionsystems. Naphthalene, borneol, benzoic acid, salicylic acid, phthalic acid and tartaric acid weremixed with γ-Al2O3 and SiO2 separately. The results showed that the organic compounds canalso disperse spontaneously onto the surfaces of different oxide-supports to become high dispersionstates like the behavior of inorganic salts and oxides. The organic substances studied are moreready to disperse with 1ess carboxyl or hydroxyl groups on their aromatic nucleus, suggesting themigration on the surface of the support is rate-determining during the dispersion. This point ofview is supported by the result of IR spectroscopy. The IR spectra of dispersed systems suggestthat the carboxy1 may react with the surface hydroxyl groups of the support to form salt-likestructures on the surface.

【基金】 国家自然科学基金!29733080
  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1998年10期
  • 【分类号】O647
  • 【被引频次】19
  • 【下载频次】209
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