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金刚石晶形显露的化学控制

Chemcal Control of Facet Appearance of Diamond

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【作者】 陈友存谢仿卿张青哲林章达

【Author】 Chen Youcun; Xie Fangqing; Zhang Qingzhe; Lin Zhangda(The State Key Laboratory of Surface Physics, Institute of Physics, Chinese Academy of Sciences,Beijing 100080)

【机构】 中国科学院物理研究所表面物理国家重点实验室!北京10008安徽省安庆市安庆师范学院化学系246011

【摘要】 采用热丝化学气相沉积法(HPCV),研究了N2、O2对金刚石晶形显露的影响。发现微量的氮气的加入([N2]/[CH4]<1%)有利于金刚石(100)晶面的显露,且不会降低金刚石晶形的完整性;微量氧的加入有利于金刚石(111)面显露.采用氧辅助控制金刚石膜(111)织构生长,可以使X射线(111)峰摇摆曲线的半宽降到6.2°.氮或氧的加入扩大了织构生长金刚石(100)或(111)膜的基片温度范围.

【Abstract】 The influence of N2 and O2 on the facet appearance of diamond has been studiedwith hot filament chemical vapor deposition (HFCVD). It was f0und that adding minor amountof N2(V(N2)/V(CH4)<1%) and O2 (V(O2)/V(CH4)20%) to the source gas is favorable for thefacet appearance of diamond (100) and (111) respectively. By the chemical control of texturedgrowtll of diamond (111) with adding O2, the FWHM of the rocking curve of X-ray (111) peakcan be reduced to 6.2° The temperature window of substrate for the textured growth of diamond(100) or (111) was enlarged with the addition of N2 or O2.

【基金】 国家自然科学基金;中关村测试基金
  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,1998年09期
  • 【分类号】O78
  • 【被引频次】3
  • 【下载频次】46
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