【摘要】 配制的电解质熔盐组成为：KF（60％）、HF（40％）．在100±5℃温度范围内电解该熔盐可制得氟气。将所制备的氟气经纯化处理后与鳞片石墨粉在500℃进行15h的反应，成功地合成制得了氟化石墨，其真密度值为2．549／cm3，含氟量为56．5％，F／C值为0．82。与石墨原料的X-射线衍射谱峰相比，所合成的氟化石墨的（002）衍射峰强度变弱，而（001）和（100）峰变宽。氟化石墨在波数1219cm（－1）和1350cm（－1）附近有F—C共价键红外光谱吸收峰。更多还原

【Abstract】 The fluorinc gas was produced by electrolysis of a mixed molten salt of KF(60%) and HF (40 %)at 100 ±5℃. After being purified, the fluorine gas was introduced into the reaction system and reacted with the scale graphite powder at 500℃ for 15h to synthesize the graphite fluoride. The synthesized graphite fluoride has a real density of 2. 54g/cm3 with its fluorine content being 56. 5%. The graphite fluoridc was also characterized by the infrared adsorption spcctrometry and the X - ray diffraction technique.更多还原