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GAS CHROMATOGRAPHIC STUDY ON THE INCLUSION PROPERTIES OF CALIX[4]ARENE DERIVATIVES

GAS CHROMATOGRAPHIC STUDY ON THE INCLUSION PROPERTIES OF CALIX4]ARENE DERIVATIVES

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【作者】 林琳严卓奇粟学莉吴采樱

【Author】 Lin Lin, Yan Zhuoqi, Su Xueli and Wu Caiying ** (Chemistry Department, Wuhan University, Wuhan, 430072)

【机构】 武汉大学化学系

【摘要】 以苯系、醇系及卤代烃系列为探测物质,用气相色谱法首次研究了两种杯[4]芳烃衍生物在气-液条件下的包结性能。结果表明:C[4]A可与苯、甲苯、甲醇、乙醇、二氯甲烷及三氯甲烷形成包结物,而C[4]B仅能与甲醇、二氯甲烷及三氯甲烷形成包结物。对其作用机理亦进行了初步探讨。

【Abstract】 The inclusion properties of two kinds of derivatized calixarene were studied with gas chromatography. Homologous series of aromatics, alcohols and halogenated hydrocarbons were used as solutes. It was found that inclusion compounds are formed between CA and benzene, toluene, methanol, ethanol, dichloromethane and chloroform and between CB and methanol, dichloromethane and chloroform.

【基金】 国家自然科学基金
  • 【文献出处】 色谱 ,CHINESE JOURNAL OF CHROMATOGRAPHY , 编辑部邮箱 ,1998年03期
  • 【分类号】O657.71
  • 【下载频次】23
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