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聚偏氟乙烯超滤膜的辐照接枝改性研究

Study on modification of polyvinylidene fluoride ultrafiltration membranes by Co 60 irradiation grafting

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【作者】 陆晓峰汪庚华梁国明刘光全王彬芳

【Author】 Lu Xiaofeng,Wang Genghua,Liang Guoming, Liu Guangquan,Wang Binfang (Shanghai Institute of Atomic Nuclear,the Academy of Sciences of China,Shanghai 201800)

【机构】 中国科学院上海原子核研究所膜分离技术研究开发中心

【摘要】 聚偏氟乙烯超滤膜经Co60辐照,接枝乙烯基单体,再经磺化,成为磺化聚偏氟乙烯超滤膜.研究了辐照剂量、接枝时间对接枝率的影响和磺化反应的条件等.试验表明,改性后膜的亲水性和抗污染性增强.此外,还讨论了膜改性的机理.

【Abstract】 Polyvinylidene fluoride ultrafiltration membranes were modified by Co 60 irradiation,grafting of vinyl unit and sulfonation in acid treating. Sulfonated polyvinylidene fluoride ultrafiltration membranes were ob tained. Irradiation dose,grafting time effected on grafting rate and the condition of sulfonation reaction were studied. The results show that the modified membranes increased the hydrophilicity and antipollution of the membranes.The mechanism of the membrane modification was discussed.

【基金】 上海市自然科学基金
  • 【文献出处】 膜科学与技术 ,MEMBRANE SCIENCE AND TECHNOLOGY , 编辑部邮箱 ,1998年06期
  • 【分类号】TQ325.4
  • 【被引频次】175
  • 【下载频次】598
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