【摘要】 以氯甲基化聚苯乙烯一二乙烯苯树脂为载体，分别合成含氯含膦配体的功能高分子，这些功能高分子化学键联MC12（M＝Fe、Co、Ni、Cr、Pd。Pt）获得固载催化剂，应用于二氧化碳与环氧乙烷合成碳酸乙烯酯的反应，具有较高活性和选择性。更多还原

【Abstract】 With chloromethylated polystyrene divinylbenezene as a support, the functional polymers containing nitrogenous ligands and phosphorous ligands were prepared.These functional polymers were chemically bound MXZ (M = Fe, Co, Ni, Cr, Pd, Pt) forming supported catalysts. By using these complexes as catalysts for reaction of carbon dioxide with oxirane to ethylene carbonate, the catalysts displayed high activity and selectivity.更多还原