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D001树脂对酸性硫脲溶液中金银的交换性能研究

STUDY ON THE EXCHANGE PROPERTIES OF GLOD AND SILVER IN ACIDIC THIOUREA MEDIUM BY D001 RESIN

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【作者】 闫英桃; 刘建; 谢华;

【Author】 Yan Yingtao; Liu Jian; Xie Hua (Department of Applied Chemistry, Xi’ an College of Geology, Xi’ an, 710054)

【机构】 西安地质学院应用化学系!西安; 10054;

【摘要】 研究了D001型大孔强酸性阳离子交换树脂从H2SO4-Tu(硫脲)溶液中,富集回收Au(Ⅰ)、Ag(Ⅰ)的性能。结果表明在pH2.0左右,树脂对Au(Tu)+2、Ag(Tu)2+有良好的吸附性能,AU和Ag的交换容量分别为61,18mg/g-R和99.11mg/g-R。负载柱上的An、Ag可分别用NaCN-NaOH和H3BO3-NaOH-Na2S2O3洗脱液定量洗脱。

【Abstract】 In this paper, the sorption and exchange properties of An(1)- thiourea and AG(1) - thiourea complex by D001 macroporous strong acidic resin from wead acid solution have been investigted. The results show that the resin can effectively adsorb Au(Tu)2+ and Ag(Tu)2+ ions (Tu = thiourea) at pH2. 0, and the static saturated adsorption capacity of resin can reach 61. 18 mg/g - resin and 99. 11 mg/g - resin for An and Ag respectively. The An(Tu)2+ and Ag(Tu)2+ adsorbed can be quantitavely eluted with NaOH - NaCN or Na2S2O3 - H3BO3 - NaOH, respectively.

【关键词】 大孔阳离子交换树脂; 硫脲; 金银;
【Key words】 Macroporous canon exchange resin; Thioures; Gold; Silver;
  • 【文献出处】 离子交换与吸附 ,ION EXCHANGE AND ADSORPTION , 编辑部邮箱 ,1998年01期
  • 【分类号】TQ425.23
  • 【被引频次】11
  • 【下载频次】114
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