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校正变换矩阵法用于四组分芳香族化合物的同时测定

APPLICATION OF CALIBRATION TRANSFORMING MATRIX METHOD IN SIMULTANEOUS DETERMINATION OF TETRADIC MIXTURES OF AROMATIC COMPOUNDS USING ULTRA-SPECTROPHOTOMETRV

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【作者】 王丽平; 司圣柱; 王红; 潘忠孝; 张懋森;

【Author】 WANG Li-ping; SI Sheng-zhu (Department of Chemistry, Anhui Institute of Education, Hefei, 230061)WANG Hong (Institute of Chemical Metallurgy, Chinese Academy of Sciences, Beijing, 100080)PAN Zhong-xiao;ZHANG Mao-sen (Department of Applied Chemistry, Unive

【机构】 安徽教育学院化学系!合肥; 230061; 中国科学院化工冶金研究所!北京; 100080; 中国科学技术大学应用化学系!合肥; 230026;

【摘要】 将目标因子分析中的自由浮动技术引入多元校正中,提出了一种新的多元校正方法。将该法用于四组分芳香化合物的紫外分光光度法同时测定。讨论了不同波长范围、不同波长间隔及校准标准溶液份数对计算结果的影响.

【Abstract】 A new multivariate calibration method based on free floating procedure of target transformation factor analysis (TTFA), called calibration transforming matrix (CTM)has been proposed for simultaneous determination of tetradic mixtures of aromatic compounds (NAP, NAA, DHN, DMO) in this paper. The optimized model of calibrating set selected for calibrated results of artificial mixtures were satisfactoried. The affecting factors,wavelength ranges, distances of wavelength points and different numbers of calibrating sets,were disscussed. It has been shown that the CTM method in some may has greater calibration capability than conventional TTFA method.

  • 【文献出处】 计算机与应用化学 ,COMPUTERS AND APPLIED CHEMISTRY , 编辑部邮箱 ,1998年02期
  • 【分类号】TQ015.9
  • 【被引频次】4
  • 【下载频次】29
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