节点文献
校正变换矩阵法用于四组分芳香族化合物的同时测定
APPLICATION OF CALIBRATION TRANSFORMING MATRIX METHOD IN SIMULTANEOUS DETERMINATION OF TETRADIC MIXTURES OF AROMATIC COMPOUNDS USING ULTRA-SPECTROPHOTOMETRV
【摘要】 将目标因子分析中的自由浮动技术引入多元校正中,提出了一种新的多元校正方法。将该法用于四组分芳香化合物的紫外分光光度法同时测定。讨论了不同波长范围、不同波长间隔及校准标准溶液份数对计算结果的影响.
【Abstract】 A new multivariate calibration method based on free floating procedure of target transformation factor analysis (TTFA), called calibration transforming matrix (CTM)has been proposed for simultaneous determination of tetradic mixtures of aromatic compounds (NAP, NAA, DHN, DMO) in this paper. The optimized model of calibrating set selected for calibrated results of artificial mixtures were satisfactoried. The affecting factors,wavelength ranges, distances of wavelength points and different numbers of calibrating sets,were disscussed. It has been shown that the CTM method in some may has greater calibration capability than conventional TTFA method.
【Key words】 TTFA; Free floating; Multivariate calibratien; Aromatic compounds; Spectrophotometry;
- 【文献出处】 计算机与应用化学 ,COMPUTERS AND APPLIED CHEMISTRY , 编辑部邮箱 ,1998年02期
- 【分类号】TQ015.9
- 【被引频次】4
- 【下载频次】29