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1.25Cr-0.5Mo中温抗氢钢的回火析出相及其对抗氢蚀能力的影响

TEMPERING PRECIPITATES OF STEEL 1.25Cr-0.5Mo AND THEIR EFFECTS ON ITS HYDROGEN ATTACK RESISTANCE

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【作者】 苏铁健罗兴宏范存淦李依依陈晓郭爱民

【Author】 SU Tiejian; LUO Xinghong; FAN Cungan; LI Yiyi (Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110015)CHEN Xiao; GUO Aimin (Wuhan Iron and Steel Company, Wuhan 430080)Correspondent: SU Tiejian, Fax: 024-3891320, Tel. 024-3843531-554

【机构】 中国科学院金属研究所!沈阳110015武汉钢铁公司!武汉430080

【摘要】 研究了中温抗氢钢125Cr—05Mo的回火析出相及其对抗氢蚀能力的影响.碳萃取复型的透射电镜观察显示,随回火温度升高,碳化物析出量增加,颗粒粗化.520和620℃回火析出物几乎全部为M3C;670℃回火析出物以M3C为主并含有少量M23C6;710℃回火主要析出M23C6,包含少量的M3C.扫描电镜观察表明,充氢之后,经620℃回火的试样发生了严重的氢腐蚀,并导致强度和硬度的大幅度下降;经520℃回火的试样在充氢后抗拉强度值下降较多;670和710℃回火试样的各项力学性能变化不大,表现了良好的抗氢蚀能力.620℃回火时沿晶界析出大量不稳定的M3C,以及在碳化物转化过程中出现的富C贫Cr区域,导致材料的氢蚀破坏.

【Abstract】 Studies were made on the tempering precipitates and their effects on hydrogen attack (HA) resistance of the medium-temperature HA-resistant Steel 1.25Cr-0.5Mo. It was shown by TEM of carbon extraction replicas that, with increasing tempering temperature, more carbides were precipitated and coarsened. When tempered at 520℃ and 620℃, almost only M3C was precipitated. When tempered at 670℃, M3C was the main precipitate with a small amount of M23C6. While tempered at 710℃, M23C6 was the main precipitate with a small amount of M3C. It was observed by SEM that,after charging hydrogen, samples tempered at 620℃ were seriously attacked by hydrogen, which resulted in great drop of strength and hardness.While no apparent HA phenomenon was observed for samples tempered at 520℃, 670℃ and710℃, but rupture strength of samples tempered at 520℃ was greatly decreased. It is related that large quantity of unstable M3C precipitated along grain boundaries, and the C-rich and Cr-poor regions for the sample tempered at 620℃ appeared, resulted in the HA degradation of the material.

  • 【文献出处】 金属学报 ,ACTA METALLRUGICA SINICA , 编辑部邮箱 ,1998年04期
  • 【分类号】TG161
  • 【被引频次】2
  • 【下载频次】175
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