【摘要】 采用能量密度为１．１７８×１０９Ｗ／ｃｍ２的ＸｅＣｌ准分子激光直接辐照高纯度的石墨靶，并同时采用辅助放电，在１×１０－５Ｔｏｒｒ的真空环境中，于温度为８０℃的Ｓｉ（１００）的基片上淀积出类金刚石薄膜，Ｒａｍａｎ光谱显示在１３３０ｃｍ－１处出现较强的散射峰值；对薄膜红外光谱进行测试，其光谱在２９００ｃｍ－１处有吸收峰，表明所淀积的类金刚石薄膜含有Ｃ－Ｈ键，其Ｈ元素与Ｃ元素的比为４５％。薄膜的电阻率为１．８９×１０６Ω／ｃｍ，通过光吸收测得的该薄膜的能隙为１５５ｅＶ。更多还原

【Abstract】 The diamondlike thin films were prepared by irradiation on high pure graphite with a high energy density(1.178×10 9W/cm 2) laser (XeCl 308nm) in 1×10 5Torr vacuum.The Raman spectra shows the thin film has the properties of diamond,the scatter peak is 1330cm -1 .The IR spectra shows the thin film contained C-H bound,and the ratio of H to C is about 45%.The resistivity and optical energy gap of the thin film are 1.89×10 6Ω/cm and 1.55eV,respectively.更多还原