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杂多酸催化合成对硝基苯甲酸乙酯
Catalytic Synthesis of Ethyl p-Nitrobenzoate by Heteropoly Acid
【摘要】 以钨锗杂多酸H4GeW12O40为催化剂,研究了对硝基苯甲酸与乙醇的液相酯化反应。考察了催化剂用量、反应时间、醇酸比等对合成产物的影响,给出了适宜的酯化工艺条件,此时对硝基苯甲酸乙酯的产率达到788%。
【Abstract】 Tungstogermanic heteropoly acid H4GeW12O40 was used as the catalyst for the esterification of p-nitrobenzoatic acid with ethyl alcohol in liquid phase.Effects of the amount of the catalyst used,the reaction time and the ratio of reactants were investigated.The suitable condition synthesizing the ester was obtained.Under the condition,the yield of ethyl p-nitrobenzoate could reach 78.8%.
【基金】 辽宁省科委基金
- 【文献出处】 化学与粘合 ,CHEMISTRY AND ADHESION , 编辑部邮箱 ,1998年02期
- 【分类号】TQ24
- 【被引频次】22
- 【下载频次】295