【摘要】 用飞行时间质谱仪对激光气化ＫＨ２ＰＯ４和Ｃｕ３（ＰＯ４）２样品形成的团簇进行了质谱研究。它们都主要形成了含有磷氧四面体价键结构的团簇。形成的［Ｋ（ＫＰＯ３）ｎ〗＋团簇系列具有明显的幻数，它们是ｎ＝３，６，９，１２，１５。这表明它们可能采取了环形三聚体的堆垛结构。［Ｃｕ（ＣｕＰＯ３）ｎ］＋可能采取了偏磷酸盐链式多聚体的结构。更多还原

【Abstract】 The clusters generated by direct laser vaporization of KH 2PO 4 and Cu 3(PO 4) 2 samples are studied by a TPF mass spectrometer.It is found that mainly the K(KPO 3) n + cluster series is generated from KH 2PO 4 sample and it demonstrates obvious magic numbers,which are n=3,6,9,12,15.Shch magic numbers strongly suggest the structure of packed potassium metaphosphate trimers.Direct laser vaporization of Cu 3(PO 4) 2 sample produced Cu(CuPO 3) n + cluster series as well as other series with the same building block of (CuPO 3).It is inferred that cupric phosphate cluster ions probably have chained structures.更多还原