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汞(Ⅱ)-碘化钾-二甲酚橙多元配合物吸光光度法测定奶制品中痕量汞

Studies and applications of spectrophotometric determination of trace amounts of mercury with multicomponent complex of Hg(Ⅱ) KI XO

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【作者】 杨振华张国文

【Author】 Yang Zhenhua , Zhang Guowen (Food, Science and Engineering Department, Nanchang University, Nanchang 330047)

【机构】 南昌大学食品科学与工程系

【摘要】 在非离子表面活性剂阿拉伯树胶和聚乙烯醇存在下,汞与碘化钾和二甲酚橙在水相中形成稳定的多元配合物显色体系。该配合物在530nm处有一最大吸收波长,汞含量在0~12μg/25mL范围内服从比耳定律,表观摩尔吸光系数高达2.43×106L·mol-1·cm-1,平均回收率97.4%~102.5%。用该法测定乳制品中痕量汞,结果令人满意。

【Abstract】 The multicomponent complex formed between mercury, potassium iodide and xylenol orange in the presence of arabic gum polyvinyl alcohol is well distributed in aqueous solution as a steady system. The maximum absorption of the multicomponent complex is at 530nm. Beer′s law is obeyed over the range of 0 ̄12μg/25mL for mercury. The molar absorptivity is 2.43 ×10 6 L·mol -1 ·cm -1 . This method has been applied to the determination of Hg(Ⅱ) in milk with satisfactory results.

  • 【分类号】O657.3
  • 【被引频次】3
  • 【下载频次】92
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