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Ag/ZnO光催化降解甲基对硫磷研究

A study on photocatalytic degradation of methylparathion by Ag/ZnO

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【作者】 岳林海周永秋

【Author】 Yue Linhai; Zhou Yongqiu,(Chemistry Department of Zhejiang University, Hangzhou 310007)

【机构】 浙江大学化学系!杭州310027

【摘要】 描述了掺杂体系Ag/ZnO用于甲基对硫磷水溶液光催化降解,发现有氧存在下、经UV照射对甲基对硫磷光降解是有效的.并讨论了影响光降解甲基对硫磷诸因素。初步探讨了光降解机理和动力学,认为起始降解物为C2H6P+S和O2NC6H4O-,且是一级反应,半衰期为1.82min。

【Abstract】 A doping system (Ag/ZnO ) for photocatalytic degradation of methylparathion (MP) aqueous solution is described. It is found that the system has the ability to degrade MP effectively by way of irradiation of UV rays.The various factors that influence the photocatalytic degradation of MP have been studied. A preliminary discussion of the photodegradation mechanism and kinetics is made. The MP initial degraded products are C2H6P+S and O2NC6H4O-. The order of MP decomposition reaction is one and its half-lived time (t1/2) is 1. 82 min.

【基金】 浙江省自然科学基金!295018(1995)
  • 【文献出处】 环境污染与防治 ,ENVIRONMENTAL POLLUTION & CONTROL , 编辑部邮箱 ,1998年03期
  • 【分类号】X703
  • 【被引频次】58
  • 【下载频次】300
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