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等离子法热解制备导电ZnO陶瓷粉

PREPARATION OF CONDUCTIVE ZnO POWDERSBY PLASMA PYROLYSIS

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【作者】 袁方利黄淑兰凌远兵李晋林

【Author】 YUAN Fangli HUANG Shulan LING Yuanbing LI Jinlin (Inst Chem Metall, Chinese Academy of Sciences, Beijing 100080,China)

【机构】 中国科学院化工冶金研究所

【摘要】 采用湿化学法制备了掺铝的碱式碳酸锌,利用等离子体条件下高温和冷却速率快的特点,使在高温热解中产生的ZnO晶格中形成更多的缺陷,提供更多的导电电子,获得较高的电导率.SEM观察粉体形貌表明,等离子体热解制得的导电ZnO粉比传统马弗炉工艺所制产品颗粒细,且粒度分布均匀,不同压力下电阻的测量结果证实了等离子体热解可以制备出导电性比传统热解工艺好的ZnO粉.

【Abstract】 Basic carbonate of zinc doped with Al was prepared by the wet chemical method The plasma pyrolysis takes advantage of high temperature and quick quenching, which may contribute to powders with more defects in ZnO crystallattice These defects provide more conducting electrons and increase ZnO powder conductivity Particle size of conductive ZnO powders produced by different ways of pyrolysis was examined by SEM It is shown that ZnO powders produced by the plasma pyrolysis are finer than those produced by the conventional pyrolysis The conductivity of the powders were measured under different pressure applied, confirming that highly conductive ZnO powders is produced 

【关键词】 等离子体热焙解导电ZnO陶瓷粉
【Key words】 PlasmaPyrolysisConductive ZnOCeramic powders
  • 【文献出处】 化工冶金 ,ENGINEERING CHEMISTRY & METALLURGY , 编辑部邮箱 ,1998年03期
  • 【分类号】TQ132.4
  • 【被引频次】23
  • 【下载频次】166
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