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用微扰理论及平均球近似关联电解质水溶液的密度
CORRELATION OF DENSITIES FOR ELECTROLYTE AQUEOUS SYSTEMS BY PERTURBATION THEORY AND MEAN SPHERICAL APPROXIMATION
【摘要】 将微扰理论和平均球近似相结合,对纯溶剂采用软球直径和色散能参数(σ和ε/k)两个可调参数,对电解质仅采用阳离子软球直径(σ+)作为唯一的可调参数,将36种纯极性溶剂和40种强电解质水溶液的密度进行了关联,结果较为满意.
【Abstract】 Correlation of densities for electrolyte aqueous systems is developed by use of the mean spherical approximation (MSA) and the perturbation theory For pure polar solvents only two adjusting parameters ( σ and ε/k) are needed and for electrolyte aqueous systems only the soft diameters of cations (σ+) are treated as the adjustable parameters The densities of 36 pure polar solvents and 40 electrolyte aqueous systems are correlated The correlation accuracy is satisfactory
【关键词】 关联;
微扰理论;
平均球近似;
密度;
电解质水溶液;
【Key words】 Correlation; Perturbation theory; Mean spherical approximation; Density; Electrolyte aqueoue solution;
【Key words】 Correlation; Perturbation theory; Mean spherical approximation; Density; Electrolyte aqueoue solution;
【基金】 国家自然科学基金
- 【文献出处】 化工冶金 ,ENGINEERING CHEMISTRY & METALLURGY , 编辑部邮箱 ,1998年01期
- 【分类号】TQ013.1
- 【被引频次】4
- 【下载频次】94