节点文献
甲酸甲酯直接水解法制甲酸的研究(Ⅰ)──反应动力学
STUDIES ON DIRECT HYDROLYSIS 0F METHYL FORMATE INTO FORMIC ACID(I)──REACTION KINETICS
【摘要】 在80℃~120℃之间对甲酸甲酯水解生成甲酸的反应动力学进行了研究,并与文献的研究结果作了比较和讨论.所得反应速率方程可表示为式中;平衡常数K则可引用文献的经验关联式.
【Abstract】 The reaction kinetics on the direct hydrolysis of methyl fomate into formic acid at temperatures of 8℃~120℃ has been investigated experimentally and compared with literature data.The reaction rate equation can be expressed as follows in which k=24556exp-6268/T)and the equilibrium constant K may be calculated by an empirical formula published in literature.
【基金】 山东省自然科学基金资助!94B-0311
- 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1998年03期
- 【分类号】TQ031
- 【被引频次】3
- 【下载频次】224