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水解聚丙烯酰胺盐水溶液表观粘度的数学模拟(Ⅳ)──存在二价金属离子时的通用MHS方程式

MATHEMATICAL SIMULATION OF APPARENT VISCOSITY FOR HYDROLYZED POLYACRYLAMIDE-SALT SOLUTION(Ⅳ)──AN UNIVERSAL MHS EQUATION IN PRESENCE OF BIVALENT METAL IONS

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【作者】 方道斌郭睿威侯永兴付小万

【Author】 Fang Daobin;Guo Ruiwei; Hou Yongxing;Fu Xiaowan(Department of Applied Chemistry,Tianjin University,Tianjin 300072)(Tianjin Research Institute of Synthetic Material,Tianjin 300220)

【机构】 天津大学应用化学系!天津300072天津合成材料研究所!天津300220

【摘要】 对于水解聚丙烯酰胺的一价金属离子和二价金属离子的混合盐水体系,提出二价阳离子对一价阳离子降低特性粘数的等效系数概念.发现这一系数仅与二价阳离子的离子强度分数有关,并可用三次多项式描述.经该系数修正的通用MHS方程式不仅仍保留了本文(Ⅰ)报原方程式的形式,而且由此修正式预测的特性粘数值与实验值吻合良好.此外还观察到阴离子Cl-、SO42-和HCO3-对特性粘数没有影响,而CO32-却使其略有增大.

【Abstract】 A concept of equivalent coefficient is proposed to describe further decreasing of intrinsic viscosities of hydrolyzed polyacrylamide─monovalent metal ions solution by the introduction of bivalent ions.It is found that equivalent coefficient is only dependent on the ionic strength fraction of bivalentmetal ions and their relationship can be expressed in a cubic polynomial.The universal MHS equation modified by equivalent coefficient still keeps the original form of the equation in Part(Ⅰ) of this series of papers and the intrinsic viscosities predicted by this modified MHS equation are in good agreement with the experimental data.In addition,it is observed that the anions such as Cl-,SO42- and HCO3- have no influence on the intrinsic viscosities,but Co32- causes it to increase slightly.

  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,1998年01期
  • 【分类号】O631
  • 【被引频次】17
  • 【下载频次】166
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