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悬浮聚合反应制备高相对分子质量PAN
PREPARATION OF HIGH MOLECULAR WEIGHT PAN BY SUSPENSION POLYMERIZATION
【摘要】 通过悬浮聚合反应,合成了高相对分子质量的聚丙烯腈(PAN)。研究了引发剂质量分数、反应温度、悬浮剂质量分数,单体配比等实验条件对聚合反应的影响以及悬浮聚合反应的动力学,对高相对分子质量聚丙烯腈溶液的流变性能作了初步研究。
【Abstract】 The synthesis and properties of high molecular weight PAN fiber prepared by suspension polymerizaion using AIBN as the initiator were investigated systematically. The effects of different experiment conditions, such as suspension agent concentration, initiator concentration and temperature on the polymerization were discussed and the kinetic model for the reaction was established. The rheological property of high molecular weight PAN spinning solution was also studied.
【关键词】 悬浮聚合;
聚丙烯腈;
反应动力学;
流变性;
【Key words】 suspension polymerization; poly(acryl nitrile); reaction kinetic; rheological property;
【Key words】 suspension polymerization; poly(acryl nitrile); reaction kinetic; rheological property;
- 【文献出处】 合成纤维工业 ,CHINA SYNTHETIC FIBER INDUSTRY , 编辑部邮箱 ,1998年04期
- 【分类号】TQ342.31,TQ316.335
- 【被引频次】32
- 【下载频次】268